When polar molecules are placed into a polar solvent (such as salt into water), the molecules will orient themselves such that the partial positive charge of one molecule can efficiently interact with the partial negative charge of an adjacent molecule. While covalent bonds do not exhibit a net charge, there can be an unequal sharing of electrons leading to an electric dipole across a bond.įor polar compounds like water, the presence of an electric dipole (partial charge on either end of the molecule) opens up opportunities for dipole-dipole interactions with other molecules. This means that oxygen, with its stronger electronegativity, will exert a stronger pull on the electrons shared between hydrogen and oxygen in the covalent bond, leading to a partial positive charge at the hydrogens, and a partial negative charge at the oxygen. The electronegativity of oxygen is 3.44, whereas the electronegativity of hydrogen is 2.20. Water is made up of 2 atoms, oxygen and hydrogen, that share electrons through a covalent bond. Atoms with higher electronegativities (such as oxygen or fluorine) will exert a stronger “pull” on electrons shared in a covalent bond.įor example, let’s look at water. As it is understood, polarity is dependent on the electronegativity of each atom in a molecule. The concept of solubility involves examining how a solute interacts with a solvent, which is primarily dictated by the polarity of both the solute and the solvent. Solubility, Intermolecular Forces and, Thermodynamics You can even bring this back to our biology to understand the interplay of lotions and our skin cells. Hence, light scattering and other “physics” concepts can be explored through lotions. Additionally, the molecules in an emulsion organize at scales similar to the wavelengths of light, which lead to an opaque appearance. We can bring the science of lotions back to the classroom in so many ways! For one, they are a great way to talk about intermolecular forces. As it turns out, lotions are a complex mixture of different substances that need to be combined - in certain proportions - in order to stably interact. We know lotions as creamy products that feel great on our skin. We encounter these types of mixtures everyday - in cosmetics, food, medicine, and some household products. To a chemist, however, lotions represent a mixture where normally immiscible (unmixable) liquids are combined in a way that evenly distributes one of the immiscible liquids into the other, without dissolving it. In terms of marketing and advertising, lotions are typically lumped into the “cosmetics” category. This is true for the water and oil components that we are working to combine in a lotion. This is because vinegar and oil are chemically incompatible. In the case of lotions, we can employ a tool such as a stick blender.Īnyone who has combined oil and water knows that, regardless of how much you mix and shake, the vinaigrette will quickly separate into the oil phase (top) and water phase (bottom). To effectively combine water-based vinegar with oil, we might use a whisk or blender. Another example of this type of mixture lies in the kitchen when making a vinaigrette. This typically requires a rigorous mechanical force to shear and disperse one liquid into the other. In creating lotion emulsions, we are combining oil-based liquids and water-based liquids such that the end product appears as a uniform substance. An emulsion is a specific type of colloid because all the components of an emulsion are liquids. Pickering emulsion biphasic catalysis green chemistry heterogeneous catalysis interfaces.Emulsions are a specific type of colloid, or a mixture where microscopic particles are dispersed - without being dissolved - throughout another substance. Challenges and future trends for the development of Pickering emulsion catalysis are finally outlined. The progress of the unconventional catalytic reactions in Pickering emulsion is further described, especially for the polarity/solubility difference-driven phase segregation, "smart" emulsion reaction system, continuous flow catalysis, and Pickering interfacial biocatalysis. Then, summarization is given to the design strategy of amphiphilic emulsion catalysts in two categories of intrinsic and extrinsic amphiphilicity. The explicit mechanism for Pickering emulsions will be initially discussed and clarified. In this review, we have comprehensively summarized the development and the catalysis applications of Pickering emulsions since the pioneering work in 2010. Pickering emulsions are particle-stabilized surfactant-free dispersions composed of two immiscible liquid phases, and emerge as attractive catalysis platform to surpass traditional technique barrier in some cases.
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Get the right Instructional designer job with company ratings & salaries. Instructional Designer - Hybrid/Remote AdMed Inc. Statement of Non-Discrimination: In keeping with our beliefs and goals, no employee or applicant will face discrimination or harassment based on: race, color, ancestry, national origin, religion, age, gender, marital/domestic partner status, sexual orientation, gender identity or expression, disability status, or veteran status. This can be downloaded from HandBrake’s official website. Some of you may be familiar with this software, but I was really happy to find it. Luckily I found a free software called HandBrake. I needed to find out what software could be used to set the footage from variable frame rate to a fixed frame rate. What to use to solve video files with variable frame rate? Finally I found an article dealing with variable frame rates on Android phones and not only. There were very few articles dealing with video speeding up during playback in Premiere Pro. As a consequence I needed to continue the investigation. Secondly, even after upgrading to Premiere Pro CC 2017 setting it to No Input, the problem persisted. First of all on the 2015 version of Premiere Pro there was no possibility to set it to No Input. Unfortunately for me the problem was somewhere else. If you have sync problems with your separate audio file I recommend to check out this setting. You can access this setting from the Edit\Preferences menu. A lot of people on the Internet confirming that setting this setting to No Input solves the problem. What I found out is that in some situations the synchronization problems was due to the Default Input of the Audio Hardware. Therefor I started doing some research on the internet. So the next on the list that I needed to investigate was whether there is some sort of bug in the Adobe Premiere Pro CC 2015 version on the file. While I have been creating 4K video in After Effects in the past with this system, I was very confident that the problem is elsewhere. the laptop on which I was editing the project wasn’t able to handle the footage ( for those who are interested it is a Lenovo G510 with Core-I3-4000M processor at 2.4Ghz and 8Gb or RAM).Adobe Premiere Pro CC 2015 has some sort of bug which is causing this problem.the recorded video, which by the way we recorded using our smartphones at 1920 x 1080 at 30 fps.My assumption was that the following things should be creating this strange phenomenon: To solve the issue I needed to make a root cause analysis to find out what could generate this behavior. But when I imported it in Premiere and dragged it on the timeline the above mentioned problems appears. If you played back the video with a normal video player everything was fine. I think that I have read at least 20-30 websites to understand what is happening. Therefore I could synchronize the video with the separate audio file. Working on one of the project I have noticed that when I imported the clip in Adobe Premiere Pro’s timeline the clip was playing fast in some portions. We will see how to solve playback issues (too fast) in Premiere Pro. Because we believe collaboration is the magic behind the movies.Does your footage plays too fast in some portions of the timeline? In this article you will find out what is the reason for that and how to solve it. Evercast allows you to stream your edit sessions in HD while video chatting and exchanging notes with your team, all under one platform. If you’re looking for a better way to bring your remote video editing team closer together and collaborate more efficiently from a distance, check out Evercast. Using these tools, you should be able to create seamless speed changes that can be used to enhance a wide variety of video projects. This one is especially handy not for sped-up video but slowed-down video as the more you slow down a video, the jerkier it can look if you didn't shoot it at a high frame rate. Optical Flow: This is another tool that uses frame duplication to add additional frames into an image to smooth out playback. If you’re looking to refine your video playback after changing the speed or direction of a clip, try using these additional tools to help you fine-tune your clip playback quality:įrame Sampling: This will delete or add additional frames for a smoother playback after changing the clip speed.įrame Blending: This will further smooth out the effect by smoothing the transition between duplicate frames added during frame sampling. Some additional tools you can use with Speed/Duration changes: Dell and the Dell logo are trademarks of Dell Inc. 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Energy, Climate Action & SustainabilityĮstimated value is Dell’s estimate of product value based on industry data, including the prices at which third-party retailers have offered or valued the same or comparable products, in its most recent survey of major online and/or off-line retailers.APEX Cloud Platform for Red Hat OpenShift.APEX Cloud Platform for Microsoft Azure.APEX Data Storage Services Backup Target. The Credit One Bank® Platinum Visa from Credit One Bank is another credit card option for those who wish to build their credit. Barclay Word MasterCard® customers can keep tabs on their creditworthiness and see if their lifestyle habits are improving or ruining their credit.ĭon’t Miss: Top Best Credit Cards for Miles | Ranking | Best Miles Credit Card Reviews The Barclaycard CashForward ™ MasterCard® account also comes with free access to your FICO credit score, a fantastic resource considering it costs money to retrieve that valuable number. 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Vanilla ® Prepaid Mastercard ® or Visa ® cards can be used anywhere Mastercard and Visa are accepted, including international locations. Vanilla Prepaid Mastercards are available in $25, $50, $60 (3 x $20), $100, and $200 values, and the Vanilla Prepaid Visa cards come in $25, $50, $75, $150 and $250 denominations. Vanilla Prepaid Mastercard or Visa cards are also sold in multiple denominations, so you can choose the exact amount you want to give. A Vanilla Prepaid Mastercard or Visa card can be bought at any Walmart Canada store and sent or given to its recipient within a Christmas greeting, birthday card or thank-you note. If you're a last-minute shopper, Vanilla ® Prepaid Mastercard ® or Visa ® cards, available from either Mastercard or Visa, are a great gift solution. Shop for Vanilla ® Prepaid Mastercard ® or Visa ® cards at Walmart Canada, which people can use just like cash to purchase anything they need or want. Gift cards are the type of presents that anyone can appreciate, whether you're buying for family members, friends or colleagues. Give the gift of a Vanilla ® Prepaid Mastercard ® or Visa ® *Trademark of Visa International Service Association and used under license by Peoples Trust Company. Vanilla ® Visa* Prepaid Card is issued by Peoples Trust Company pursuant to license by Visa Int. Mastercard is a registered trademark, and the circles design is a trademark of Mastercard International Incorporated. Vanilla ® Prepaid Mastercard ® is issued by Peoples Trust Company under license by Mastercard International Incorporated. See Cardholder Agreements for more details at. Card is subject to maximum transaction limits. Funds may not be available on card for the first twenty-four (24) hours after purchase. Card will not be accepted for pay-at-the-pump transactions. Card may be deactivated at any time if fraud is suspected. Use of the card may be restricted at some online merchants. Use of the card in certain countries may be restricted by law. You may not make pre-authorized regular payments through the card. Card is not reloadable and cannot be used to make cash withdrawals. For a fee of $9.95, you can also elect to close the card, liquidate the balance and receive a paper check in the mail.Card is not returnable or refundable. In the event your card is lost or stolen, a $6 replacement fee will be assessed. In addition, a $0.50 fee applies to all signature and PIN purchases. There is no monthly fee, but a dormancy fee of $3.95 will apply if the card is not used for a period spanning 90 days. Direct deposit: If your employer offers direct deposit, you can have your paycheck sent directly to your card.Text and email alerts: You can opt-in to receive text and email alerts about account updates.Cash back at the point of sale: A $1.95 fee applies for over-the-counter cash back transactions.FDIC Insurance: The card's balance is insured through The Bancorp Bank, which is an FDIC member.Transfers are limited to $500 daily and $2,000 monthly. Card-to-card transfer: Funds can be transferred between Vanilla Visa products.If the card is declined, a $0.75 fee will be assessed. The fee is $4.95 for international transactions. ATM access: A $1.95 fee applies for domestic transactions.Online bill payment: The card has both recurring and automatic online bill payment capabilities.It is also accompanied by free direct deposit and an array of other benefits, including: The maximum daily and monthly reload amounts are $2,500 and $5,000, respectively. Unlike the other Vanilla Visa products, this card is customized with the holder's name and can be reloaded using Vanilla Reload or Walmart Rapid Reload. The MyVanilla Personal Reloadable Visa Card is a money-management tool designed to be a plastic alternative to a traditional bank account rather than a gift card. You can identify forward-looking statements by the fact that they do not relate strictly to historical or current facts. Forward-looking statements discuss the Company's current expectations and projections relating to its financial position, results of operations, plans, objectives, future performance and business. This document, taken together with any such verbal or written comments, is referred to herein as the "Presentation."Īll statements other than statements of historical fact included in this presentation are forward-looking statements, including, but not limited to, timing of new venue openings, expected financial outlook for fiscal 20, expected operating performance, time of construction start dates and milestones, expected sales and trends in Drive Shack Inc.'s (the "Company's") operations including statements relating to the effects of COVID-19 and our ability to achieve our growth plans and goals. This disclaimer applies to this document and the verbal or written comments of any person presenting it. ©2022 Drive Shack Inc.Ĭautionary Note on Forward-Looking Statements and 9am-midnight on Sun.EARNINGS PRESENTATION - FIRST QUARTER 2022ĬONFIDENTIAL: May only be used with consent. Cornhole tournaments may appear on the future schedule as well.ĭrive Shack is open seven days a week, from 10am-midnight, Mon.-Thurs., 10am-2am on Fri., 9am-2am, on Sat. On the rooftop patio, space for live music and comedy nights is expected to be in use on a weekly basis. On the second floor, a free-to-play arcade room features Golden Tee, Skee-Ball, shuffleboard, mini basketball goals and more. Larger groups of 12 or more can book party packages in advance. The restaurant and bars, including the rooftop area, are also always open to guests who don't plan to use the golf facilities. The food and drink menu consists of burgers, wings, tacos, nachos, salads, local craft beer, cocktails and more (if there's no wait, you can eat and drink while hitting golf balls or relaxing at your bay). For those times, the bar and restaurant area are more than happy to keep you occupied. Happy hour and late-night specials may also appear on the venue's calendar.īay rentals are done on a first-come, first-served basis, so a wait could be expected during evenings and weekends. During peak times-typically after 5pm-a maximum price of $40-50 per hour is in place to rent an entire bay (meaning each person pays less than $10 per hour if you bring a group of six). Pricing varies based on time and day, but starts at $10 per person, per hour (a group of three would pay a total of $30 per hour around lunchtime, for example). The range utilizes TrackMan technology, pinpointing the flight of your golf ball and allowing you to virtually play real-world championship golf courses or go head-to-head against friends to collect points for hitting physical targets (games are tracked and scored on television screens inside your bay). The 260-yard-long driving range combines physical targets to aim for with augmented reality and virtual games. (the first opened in Orlando in 2018).ĭrive Shack allows guests and groups to rent bays by the hour, giving them access to wait-service, unlimited driving range balls, full sets of TaylorMade golf clubs, a climate-controlled seating area, televisions and more. This is the second Drive Shack location to open in the U.S. The 65,000-square-foot facility includes 96 golf bays, a full-service restaurant, a rooftop bar, more than 300 televisions, an arcade area, meeting rooms and more. The three-story complex with ample free parking is located at 6901 Play Golf Way (not far from PNC Arena). Ready for some big entertainment news? A major new attraction has swung into action in the City of Oaks!ĭrive Shack-the interactive golf complex that caters to big groups looking for big fun-opened in Aug. in Raleigh, N.C. He incorporated pop, hip-hop, rock, worship, even spoken word, and a few rap songs along the way, to create a genre that is every way different and maybe even a sub-set of a genre that is only synonymously attributed to him- a Carman genre- maybe his counterpart at the moment who is able to blend in a vast amount of musical styles and genres to form their own, would have to be TobyMac. Among the first of the artists my parents introduced me to that set me down a path of CCM that opened doors to other artists like Delirious?, Steven Curtis Chapman, Tim Hughes and the Newsboys (to name a few), Carman’s ministry through music was always hard-hitting and ground breaking. of years active in said industry.Ĭarman’s music was featured heavily during the 1980s and 1990s, and while post-2000, there wasn’t really much album releases from a guy whose niche genre of gospel/story-songs/spoken word wasn’t as welcomed or even expected in an industry that’s ever growing (which is indeed very sad upon reflection), Carman still holds a special place in my heart. Influence and impact are rather more about lives changed and positively altered than the no. Carman’s impact far goes beyond years active in the industry. Carman may or may not be making music at the moment, but even that is irrelevant. And for that instilling of the Word of God, I’m proud to rekindle my love, appreciation and respect for Carman’s music as I prepared a little for this blog post this week. 2 in who taught our family around the 1990s (cause that’s when I grew up) about the gospel of Jesus Christ and what it meant to follow Jesus on a daily basis. Apart from the Bible and Jesus, Carman was No. Maybe my comparison to such greats within the CCM industry can seem to some as being a little naïve about the actual real impact of Carman on music, but for me personally, Carman’s influence in indeed second to none. Born Carman Licciardello (and known by his stage name ‘Carman’) in the mid-1950s, his music quite literally shaped our view of God and who we (myself and my twin brother) are today- he may not be influential at this very moment in music, but throughout CCM and CCM history, as well as the lives of myself and Josh my brother, Carman was very much an artist that indeed is a pioneer, into the category of others like Amy Grant, Larry Norman, Rich Mullins, PETRA and Keith Green. And which music artist did they turn to for such biblical knowledge, understanding and songs that allowed what we knew about God and Jesus and everything else to soak into our lives from when we were young till now? Why, Carman of course. What is the point is that in the Christian home and family I grew up in, music as a way of imparting positive and godly values and instilling them in lives such as mine and my brother’s at a young age was almost a non-negotiable for our parents. Yes, way back when I was in nappies, and learning to walk, I was listening to music at a ripe young age of…well, I don’t know, but that’s beside the point. If you were to pick one artist that has shaped me as a person and that has managed to sow seeds of hope, encouragement and the love of Christ when I was young, then Carman was the guy. Carman has had one of the greatest impacts in my life from as early as I know to this very day. One such artist that I’m about to delve into at the moment, is 1990s and 2000s CCM legend, Carman!Ĭarman has made a big impact on my life. Still, here I am back, and ready to get into yet another year of exploring artists that I believe have made a mark on today’s music culture, amongst people, and shaped music in general. To put it bluntly, I found a little of my identity in my blog post series this past year. I was letting this blog series take control of my life, not necessarily consciously, but nevertheless, that’s what I was doing. Over this month when I wasn’t immersing myself into this particular artist and that, I found out how much time I was undertaking the discovery of new artists throughout the year. I’ve learnt to slow down a little during my time away, and to remind myself that though this year has been great as I’ve explored a vast myriad of music at my fingertips quite literally (you can search on Youtube for any musical content you wish!) my life wasn’t just music. Yes, I did turn the big proverbial 3 0 on last week Monday, and after a big long break of just over a month between the last previous blog (Week 34 was for KING AND COUNTRY published online in mid-November) and now, I’ve managed to catch up on a very much needed time of rest, relaxation, and just generally working hard at my work as a café owner and operator. That’s a big loaded statement to start off my next blog post. The Elantra range includes two self-charging hybrid optionsĮngine choice in the Elantra includes a 2.0L option and a 1.6L turbocharged engine from the gasoline-only range. More importantly, the Elantra range includes two self-charging hybrids with the best mpg figures we’ve seen so far. This is their entry-level sedan and comes in seven trim levels. Moving away from Hyundai SUVs, we have the Elantra next. Highway driving distance on a single tank of fuel: 393 milesĢ.Urban driving distance on a single tank of fuel: 345 miles.With a fuel capacity of 11.9 gallons, you should achieve a journey of: The Venue is designed as a perfect city crossover, and for that purpose, you won’t need to run hundreds of miles in one go. As the Venue is the smallest Hyundai SUV, we wouldn’t expect a larger fuel tank here. With a fuel tank size of just under 12 gallons, this isn’t a great car for regular long journeys. The Venue is only available in front-wheel drive, so gas mileage isn’t impacted here. This gets you 121 bhp and more importantly, an average of 31 mpg combined. With a single engine choice, the Venue comes with a 1.6-Liter naturally aspirated engine. Starting at under $20,000, this is a great SUV if you’re on a budget, but how expensive is it to run? The Venue only comes with a single engine option This is Hyundai’s entry-level SUV and their smallest non-car model. Highway driving distance on a single tank of fuel: 436 – 462 miles.Urban driving distance on a single tank of fuel: 370 – 396 miles.With a fuel capacity of 13.2 gallons, you should achieve a journey of: This isn’t exceptional for SUVs like this, but it’s still capable of getting you through longer journeys without too many issues. With a fuel tank size of just over 13 gallons, there are around 400 miles available in a full tank in the Kona. We’ve left out the Kona N on this comparison, though – as the performance model, it’s a very different car, and with 276 bhp the fuel economy takes a big hit. Overall though, with between 147-195 bhp, the Kona can boast decent gas mileage for a car like this. The Kona comes with two engine options, and the choice to include all-wheel drive The Kona also comes with the option of all-wheel drive, which hurts fuel economy figures slightly. This small SUV comes with a couple of engine choices a 2-Liter naturally aspirated option or a 1.6L turbocharged engine. We’ll cover other vehicles later, but for now, if you want a lot of gas mileage for your money, these are the Hyundais to go for. The below section covers gasoline and self-charging hybrid models in the Hyundai range. Tucson Plug-In Hybrid: 35 (Urban) / 35 (Highway).Santa Fe Plug-In Hybrid: 33 (Urban) / 33 (Highway).carwow Ltd is registered in England (company number 07103079), registered office 2nd Floor, Verde Building, 10 Bressenden Place, London, England, SW1E 5DH. All finance offers and monthly payments shown are subject to application and status. carwow is covered by the Financial Ombudsman Service (please see more information). carwow may receive a fee from retailers advertising finance and may receive a commission from partners (including dealers) for introducing customers. carwow is a credit broker and not a lender. carwow is the trading name of carwow Ltd, which is authorised and regulated by the Financial Conduct Authority for credit broking and insurance distribution activities (firm reference number: 767155). Vehicle returned at term end.Īverage savings are calculated daily based on the best dealer prices on carwow vs manufacturer RRP. Illustrations are based on personal contract hire, 9 month upfront fee, 48 month term, 8000 miles annually, inc VAT, excluding fees. Quote is subject to dealer requirements, including status and availability. Please contact the dealer for a personalised quote, including terms and conditions. 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